English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Zendy Plus

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Zendy Tools

Zendy Open

By means of electron paramagnetic resonance (EPR) measurements on thermally reduced Cr-doped SrTiO3, we find a strong correlation between the Cr3+ ions and oxygen vacancies (Vos). A charge compensation associated with the creation of Vos induced by thermal reduction causes the valence of the Cr ions to change from 4+ to 3+. This induces a symmetry change in the crystal field experienced by the Cr atom from cubic to axial. On the other hand, in Cr/Nb-codoped samples, where Vos are absent, the Cr3+ EPR signal is isotropic, indicating that these Cr ions occupy an octahedral site of cubic symmetry. From the angular dependence of the EPR spectra we determine an axial crystal field parameter (D≃8 MHz), which is consistent with a perturbation induced by a Vo localized at the third coordination sphere of Cr3+. This is in contrast to other transition-metal dopants, where the Vo is located at the first coordination sphere. Thus we identify a linear complex of the form Cr3+-O-Ti3+-Vo-Ti3+, which is unique in its structure, and which, furthermore, might account for the stabilization of the insulating state in reduced Cr-doped SrTiO3 crystals

physical review b

Controlled oxygen vacancies and space correlation with<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msup><mml:mrow><mml:mtext>Cr</mml:mtext></mml:mrow><mml:mrow><mml:mn>3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mtext>SrTiO</mml:mtext></mml:mrow><mml:mn>3</mml:mn></mml:msub></mml:mrow></mml:math>

Controlled oxygen vacancies and space correlation withCr3+inSrTiO3