English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

Despite extensive research on the skutterudites for the last decade, theirelectric crystalline field ground state is still a matter of controversy. Weshow that Electron Spin Resonance (ESR) measurements can determine the full setof crystal field parameters (CFPs) for the Th cubic symmetry (Im3) of theCe$_{1-x}$R$_{x}$Fe$_{4}$P$_{12}$ (R = Dy, Er, Yb, $x\lesssim 0.003$)skutterudite compounds. From the analysis of the ESR data the three CFPs, B4c,B6c and B6t were determined for each of these rare-earths at the Ce$^{3+}$site. The field and temperature dependence of the measured magnetization forthe doped crystals are in excellent agreement with the one predicted by theCFPs Bnm derived from ESR.

physical review. b, condensed matter and materials physics

Direct determination of the crystal field parameters of Dy, Er and Yb  impurities in the skutterudite compound CeFe$_{4}$P$_{12}$ by Electron Spin  Resonance