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The nature of charge carriers and their interaction with local magnetic moments in an oxide magnetic semiconductor is established. For cobalt-doped anatase TiO2 films, we demonstrate conduction in a metallic donor-impurity band. Moreover, we observe a clear signature of the Kondo effect in electrical transport data with remarkably high Kondo temperatures of up to 120 K. This indicates a strong coupling between local Co moments and delocalized electrons in the impurity band

physical review b

Kondo effect and impurity band conduction in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:mi mathvariant="normal">Co</mml:mi><mml:mo>:</mml:mo><mml:mi mathvariant="normal">Ti</mml:mi><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:mrow></mml:math>magnetic semiconductor

Kondo effect and impurity band conduction inCo:TiO2magnetic semiconductor