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Static magnetic susceptibility \chi, ac susceptibility \chi_{ac} and specificheat C versus temperature T measurements on polycrystalline samples of In2VO5and \chi and C versus T measurements on the isostructural, nonmagnetic compoundIn2TiO5 are reported. A Curie-Wiess fit to the \chi(T) data above 175 K forIn2VO5 indicates ferromagnetic exchange between V^{4+} (S = 1/2) moments. Below150 K the \chi(T) data deviate from the Curie-Weiss behavior but there is nosignature of any long range magnetic order down to 1.8 K. There is a cusp at2.8 K in the zero field cooled (ZFC) \chi(T) data measured in a magnetic fieldof 100 Oe and the ZFC and field cooled (FC) data show a bifurcation below thistemperature. The frequency dependence of the \chi_{ac}(T) data indicate thatbelow 3 K the system is in a spin-glass state. The difference \Delta C betweenthe heat capacity of In2VO5 and In2TiO5 shows a broad anomaly peaked at 130 K.The entropy upto 300 K is more than what is expected for S = 1/2 moments. Theanomaly in \Delta C and the extra entropy suggests that there may be astructural change below 130 K in In2VO5.

Magnetic and thermal properties of the S = 1/2 zig-zag spin-chain compound In2VO5