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Inelastic effects in the Coulomb blockade and Kondo regimes of electrontransport through molecular junctions are considered within a simplenonequilibrium equation-of-motion (EOM) approach. The scheme isself-consistent, and can qualitatively reproduce the main experimentalobservations of vibrational features in Coulomb blockade [H.Park et al., Nature407, 57 (2000)] and Kondo [L.H.Yu et al., Phys. Rev. Lett. 93, 266802 (2004)]regimes. Considerations similar to the equilibrium EOM approach by Meir et al.[Phys. Rev. Lett. 66, 3048 (1991); ibid. 70, 2601 (1993)] are used on theKeldysh contour to account for the nonequilibrium nature of the junction, anddressing by appropriate Franck-Condon (FC) factors is used to account forvibrational features. Results of the equilibrium EOM scheme by Meir et al. arereproduced in the appropriate limit.

Inelastic effects in molecular junctions in the Coulomb and Kondo regimes: Nonequilibrium equation-of-motion approach