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The atomic and electronic structure of the lattice-mismatched  h-BN/Pt(111) and h-BN/Rh(111) interfaces formed by pyrolitic reactions  with vaporized borazine has been studied by low-energy electron  diffraction, scanning tunneling microscopy, x-ray-absorption  spectroscopy, and core-level and valence-band photoemission. It has been  found that on Pt(111), h-BN forms a nearly flat monolayer,  insignificantly corrugated across the supercell. On Rh(111), h-BN grows  in form of a nanomesh, as originally observed by Corso [Science 303, 217  (2004)]. The structural difference between the h-BN/Pt(111) and  h-BN/Rh(111) interfaces is associated with the strength of chemical  interaction between h-BN and the substrate surface. A stronger orbital  hybridization on Rh(111) results in a stronger attraction of the  monolayer to the metal surface at favorable adsorption sites resulting  in a highly corrugated structure (nanomesh). It has been shown that the  electronic structure of the outer (elevated) and inner (attracted to the  surface) nanomesh sites is very different as a result of different  chemical bonding to the substrate (weak and strong, respectively)

physical review b

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Influence of chemical interaction at the lattice-mismatchedh−BN∕Rh(111)and<…