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It has been found that aliovalent-substituted $\mathrm{Bi}\mathrm{Fe}{\mathrm{O}}_{3}\text{\ensuremath{-}}\mathrm{Pb}\mathrm{Ti}{\mathrm{O}}_{3}$-based polycrystalline materials have significantly enhanced multiferroic properties. Relative to unmodified $\mathrm{Bi}\mathrm{Fe}{\mathrm{O}}_{3}$, our results for modified $\mathrm{Bi}\mathrm{Fe}{\mathrm{O}}_{3}\text{\ensuremath{-}}\mathrm{Pb}\mathrm{Ti}{\mathrm{O}}_{3}$-based ceramics reveal: (i) a dramatic increase in the electric-field-induced polarization; and (ii) the establishment of a remanent magnetization. The results evidence the destruction of a space-modulated spin structure in bulk materials, via substituent effects, releasing a latent magnetization locked within the cycloid.

physical review b

Multiferroic properties of modified<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:mi mathvariant="normal">Bi</mml:mi><mml:mi mathvariant="normal">Fe</mml:mi><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:mtext>−</mml:mtext><mml:mi mathvariant="normal">Pb</mml:mi><mml:mi mathvariant="normal">Ti</mml:mi><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:mrow></mml:math>-based ceramics: …

Multiferroic properties of modifiedBiFeO3−PbTiO3-based ceramics: …