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Individual Cu-phthalocyanine molecules have been investigated by scanning tunnel microscopy on a closed packed film of C-60 at various temperatures. The molecules are found to bind asymmetrically to one C-60. While they remain in one position at low temperature, they can hop between six equivalent positions at higher temperatures performing a hindered eccentric rotation around the binding C-60 molecule. At room temperature only the time average over different positions is observed

physical review. b, condensed matter

Direct observation of hindered eccentric rotation of an individual molecule: Cu-phthalocyanine on<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">C</mml:mi></mml:mrow><mml:mrow><mml:mn>60</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>

Direct observation of hindered eccentric rotation of an individual molecule: Cu-phthalocyanine onC60