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We use the Quantum Hypernetted Chain Approximation (QHNC) to calculate theion-ion and electron-ion correlations for liquid metallic Li, Be, Na, Mg, Al,K, Ca, and Ga. We discuss trends in electron-ion structure factors and radialdistribution functions, and also calculate the free-atom and metallic-atomform-factors, focusing on how bonding effects affect the interpretation ofX-ray scattering experiments, especially experimental measurements of theion-ion structure factor in the liquid metallic phase.

Probing ion-ion and electron-ion correlations in liquid metals within the quantum hypernetted chain approximation