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The elemental metals Ga and Tl are studied under pressure in a diamond anvil cell by energy dispersive x-ray diffraction. While Tl remains in the high-pressure cF4 structure up to the highest pressures achieved, several phase transitions are observed in Ga. Different equation-of-state (EOS) forms are fitted to the experimental data. A detailed analysis of the data shows that a simple first-order EOS form can describe the isothermal pressure-volume behavior of all the phases for Ga as well as for Tl. Furthermore, a comparison of the structural behavior under pressure is made for all the group-IIIA elements of the Periodic Table

Effect of pressure on the atomic volume of Ga and Tl up to 68 GPa