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The variety of excitonic states in tungsten-based dichalcogenide monolayersstems from unique interplay between the spin and valley degrees of freedom. Oneof the exciton species is the indirect exciton (momentum or valley dark), whichis responsible to a series of resonances when the monolayer is charge neutral.We investigate the short-range electron-hole exchange interaction of theindirect exciton, as well as its recombination mechanism mediated byimpurities. The analysis provides thorough understanding of the energy andpolarization of the zero-phonon indirect exciton resonance in the emissionspectrum.

Intervalley electron-hole exchange interaction and impurity-assisted recombination of indirect excitons in WS$_2$ and WSe$_2$ monolayers