English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

We compare the trends on the strength of electronic correlations across thedifferent phases of elemental Pu focusing on its site and orbital dependence,using a combination of density functional theory (DFT) and dynamical mean fieldtheory (DMFT) calculations within the vertex corrected one crossingapproximation. We find that Pu-5$f$ states are more correlated in $\delta$-Pu,followed by some crystallographic sites in $\alpha$ and $\beta$ phases. Inaddition, we observe that Pu-5$f_{5/2}$ and Pu-5$f_{7/2}$ orbitaldifferentiation is a general feature of this material, as is sitedifferentiation in the low symmetry phases. The Pu-5$f_{5/2}$ states show Fermiliquid like behavior whereas the Pu-5$f_{7/2}$ states remaining incoherent downto very low temperatures. We correlate the correlation strength in thedifferent phases to their structure and the Pu-5$f$ occupancy of theircrystallographic sites.

Correlation strength and orbital differentiation across the phase diagram of plutonium metal