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Two different Master Equation approaches have been formally derived toaddress the dynamics of open quantum systems interacting with a thermalenvironment (such as sunlight). They have led to two different physicalresults: non-secular equations that show noise-induced (Fano) coherences andsecular equations that do not. An experimental test for the appearance ofnon-secular terms is proposed using Ca atoms in magnetic fields excited bybroadband incoherent radiation. Significantly different patterns offluorescence are predicted, allowing for a clear test for the validity of thesecular and non-secular approach and for the observation of Fano coherences.

Secular vs. Non-secular Redfield Dynamics and Fano Coherences in Incoherent Excitation: An Experimental Proposal