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The static dipole polarisability of noble gas atoms confined by impenetrablespheres and spherical shells is studied using the B-spline random phase withexchange approximation. The general trend in dipole polarisabilities across thenoble gas sequence shows a decrease in the dipole polarisability as the volumeof the confining impenetrable sphere is reduced and a large increase in thedipole polarisability for confinement by impenetrable spherical shells as theinner shell radius is increased.

Investigating the static dipole polarisability of noble gas atoms confined in impenetrable spheres and shells