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A systematic study of the leading isotropic van der Waals coefficients forthe alkali-metal atom + molecule and molecule + molecule systems is presented.Dipole moments and static and dynamic dipole polarizabilities are calculatedemploying high-level quantum chemistry calculations. The dispersion, induction,and rotational parts of the isotropic van der Waals coefficient are evaluated.The known van der Waals coefficients are then used to derive characteristicsessential for simple models of the collisions involving the correspondingultracold polar molecules.

Van der Waals coefficients for systems with ultracold polar alkali-metal molecules