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We report an upper bound to the ionization energy of 85Rb2 of 31348.0(6)cm-1, which also provides a lower bound to the dissociation energy D0 of 85Rb2+of 6307.5(6) cm-1. These bounds were measured by the onset of autoionization ofexcited states of 85Rb2 below the 5s+7p atomic limit. We form 85Rb2 moleculesvia photoassociation of ultracold 85Rb atoms, and subsequently excite themolecules by single-photon ultraviolet transitions to states above theionization threshold.

Upper Bound to the Ionization Energy of 85Rb2