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We report the first observation of photoassociation to the 2(1)Sigma(g)(+)state of 85Rb2 . We have observed two vibrational levels (v'=98, 99) below the5s1/2+5p1/2 atomic limit and eleven vibrational levels (v'=102-112) above it.The photoassociation---and subsequent spontaneous emission---occurpredominantly between 15 and 20 Bohr in a region of internuclear distance bestdescribed as a transition between Hund's case (a) and Hund's case (c) coupling.The presence of a g-wave shape resonance in the collision of two ground-stateatoms affects the photoassociation rate and lineshape of the J'= 3 and 5rotational levels.

Photoassociation to the 2(1)Sigma(g)(+) state in ultracold 85Rb2 in the presence of a shape resonance