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The tremendous development of cold atom physics has opened up a whole newopportunity to study novel states of matter which are not easily accessible insolid state systems. Here we propose to realize the $f$-wave pairingsuperfluidity of spinless fermions in the $p_{x,y}$-orbital bands of the twodimensional honeycomb optical lattices. The non-trivial orbital band structurerather than strong correlation effects gives rise to the unconventional pairingwith the nodal lines of the $f$-wave symmetry. With a confining harmonic trap,zero energy Andreev bound states appear around the circular boundary with asix-fold symmetry. The experimental realization and detection of this novelpairing state are feasible.

$F$-wave pairing of cold atoms in optical lattices