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This work presents accurate ab initio determination of the hyperfinesplitting for the ground state and few low-lying excited states of 113Cd+;important candidates for the frequency standard in the microwave region, usingcoupled-cluster theory (CC) in the relativistic framework. The calculatedhyperfine splitting are well in agreement with recent experimental results. Wehave also carried out the lifetimes of the 5p2P1=2 and 5p2P3=2 states, whichare in well agreement with recent experimental result (Moehring et al., PRA 73023413, 2006). The roles of different electron correlation effects in thedetermination of these quantities are discussed and their contributions arepresented in the CC terms.

Ab initio relativistic many-body calculation of hyperfine splitting of ^{113}Cd^+