Retarded dipole-dipole dispersion interaction potential for helium
Author(s) -
M. J. Jamieson,
G. W. F. Drake,
A. Dalgarno
Publication year - 1995
Publication title -
physical review a
Language(s) - English
Resource type - Journals
eISSN - 1094-1622
pISSN - 1050-2947
DOI - 10.1103/physreva.51.3358
Subject(s) - physics , dipole , helium , inverse , electric dipole transition , dispersion (optics) , atomic physics , simple (philosophy) , scattering , quantum electrodynamics , magnetic dipole , quantum mechanics , geometry , mathematics , philosophy , epistemology
The retarded dipole-dipole dispersion interaction potential in helium is evaluated from a set of very accurate effective dipole transition frequencies and oscillator strengths already obtained from a variational calculation. The asymptotic form changes from the inverse sixth to the inverse seventh power of the nuclear separation as the atoms move apart. Simple representations of the potential are given for use in scattering and structure calculations.
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