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Ion mobilities of Lr^+ (Z = 103) and of its lighter chemical homolog Lu^+ (Z= 71) in helium were calculated for the ground state ^1S_0 and the lowestmetastable state ^3D_1. To this end we applied the multi-referenceconfiguration interaction (MRCI) method to calculate the ion-atom interactionpotentials in the different states. The Gram-Charlier approach to solving theBoltzmann equation was used to deduce the mobilities of the differentelectronic states, based on the calculated interaction potentials. We foundthat the zero-field ion mobilities are similar for the Lr^+ and Lu^+ ions. Inaddition, the ion mobilities of the different states are substantiallydifferent for temperatures above 100K. The relative differences between themobilities of the ground and excited states at room temperature are about 15\%and 13\% for Lu^+ and Lr^+ ions, respectively, which should be sufficientlylarge enough to enable laser resonance chromatography (LRC) of these ions.

State-specific ion mobilities of Lr^+ (Z = 103) in helium