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Electron-induced dissociative excitation (DE) is a little studied process of significant applied relevance. Our aim is to provide a theoretical counterpart to earlier experiments [M. J. Jensen, R. C. Bilodeau, O. Heber, H. B. Pedersen, C. P. Safvan, X. Urbain, D. Zajfman, and L. H. Andersen, Phys. Rev. A 60, 2970 (1999)] on DE of H$_2$O$^+$. For this purpose, we have performed low-energy fixed-nuclei scattering calculations, based on the R-matrix method, for over 1800 geometries of H$_2$O$^+$. We have identified and characterized three resonances lying above the second (B) excited state of H$_2$O$^+$; their energy, lifetime, and associated quantum defect have been determined. We assess their possible contribution to the DE process.

physical review. a/physical review, a

Toward a description of electron-induced dissociative excitation in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">H</mml:mi></mml:mrow><mml:mn>2</mml:mn></mml:msub><mml:msup><mml:mrow><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math> : Investigation of three resonances above the <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mover accent="true"><mml:mi>B</mml:…

Toward a description of electron-induced dissociative excitation in H2O+ : Investigation of three resonances above the B