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A new approach was developed for the synthesis of 4'-modified neplanocin A, as potential inhibitors against S-adenosyl-L-homocysteine hydrolase. Vinylstannane derivative 5, a key intermediate in the present approach, was prepared by radical-mediated sulfur-extrusive stannylation.

Synthesis of novel 4'-modified neplanocin A analogues based on radical-mediated sulfur-extrusive stannylation