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Reaction channels and spectroscopic properties of a series of silicon–carbon-bearing isomers of SiC3H+ and SiC3H, which are suitable species for astrophysical detection in carbon-rich sources, are calculated with correlated ab initio CCSD(T) and density functional theory methods. We present four isomers of SiC3H+ for which the electronic ground states have closed-shell configurations. For SiC3H, w...

Reaction channels and spectroscopic constants of astrophysical relevant Silicon bearing molecules SiC3H,+ and SiC3H