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Enantioselective gas chromatography (GC) with 5 modified cyclodextrins was applied to chiral organochlorines. A prerequisite for determining GC elution orders of enantiomers is the availability of enantioenriched standard solutions. In addition to compounds reported before (e.g., α-HCH, PCB 174, oxychlordane), we determined the sign of optical rotation of enantioenriched solutions of e-aeee-pentachlorocyclohexene-1 (β-PCCH), perdeuterated α-HCH (α-PDHCH), perdeuterated β-PCCH, and the persistent compound of technical toxaphene—2-exo,3-endo,5-exo,9,9,10,10-heptachlorobornane (B7-1453)—by liquid chromatography (LC) with a chiral detector. An enantioenriched solution of (β-PCCH was obtained by enantioselective degradation of α-HCH with (-)-brucine. In addition to forming an enantiomeric excess of (-)-α- HCH, we formed enantioenriched (+)-(α-PCCH. In a similar study, α-PDHCH showed the same behavior with respect to enantioselectivity. Dextrorotation of an enantioenriched solution of B7-1453 was also confirmed by LC with a chiral detector. Enantioseparation of chiral organochlorines on 5 chiral stationary phases resulted in several reversed elution orders. These results indicate that a careful check of elution orders of organochlorine enantiomers is necessary prior to comparison of literature data for the study of enantioselective processes in the environment.

journal of aoac international

Determination of (+/−) Elution Orders of Chiral Organochlorines by Liquid Chromatography with a Chiral Detector and by Enantioselective Gas Chromatography