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Metal–organic frameworks (MOFs) are a class of novel porous materials consisting of clusters or chains of metal ions and organic linkers. The chiral MOF [Cd(LTP) 2 ]  n   (LTP =  l (−)-thiazolidine-4-carboxylic acid) possesses infinite extension three-dimensional supramolecular reticular structure with right-handed helix. In this work, three capillary columns (A, B and C) containing MOF [Cd(LTP) 2 ]  n  , permethylated β-cyclodextrin (CD) and sodium chloride, and MOF [Cd(LTP) 2 ]  n   and permethylated β-CD, respectively, have been prepared and their respective enantioseparation abilities have been investigated. The polarities of all of the MOFs and permethylated β-CDs are moderate. The numbers of theoretical plates (plate m −1 ) of the three columns have been measured using  n -dodecane at 120°C, which followed an increasing order of A (3100) &lt; B (3800) &lt; C (4300). Some racemates were separated with different resolutions on Columns A, B and C. The results indicated that the incorporated MOF [Cd(LTP) 2 ]  n   enhanced the separations of racemates on a permethylated β-CD stationary phase with high column efficiency and good reproducibility in gas chromatography.

Metal–Organic Framework [Cd(LTP) 2 ] n for Improved Enantioseparations on a Chiral Cyclodextrin Stationary Phase in GC