English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Zendy Plus

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Zendy Tools

Zendy Open

A separation mechanism of eight Co(III) complexes with ethylenediaminetetraacetate-type ligands belonging to two series during salting-out thin-layer chromatography on silica gel is investigated. The sorbent is impregnated with five poly(ethylene glycol)s with different molecular masses, and ammonium sulphate solutions are used as mobile phase. Additionally, on non-impregnated sorbent, mobile phases containing one of eight salts with ions of different lyotropic properties are used: kosmotropic Mg 2+  accompanied with SO 4  2–  (kosmotrope), Cl −  (border), NO 3  −  (chaotrope), ClO 4  − (chaotrope), Cl −  of Li +  (kosmotrope), Na +  (border), K +  (chaotrope) and NH 4  +  (chaotrope). Salting-out and salting-in effects were observed depending on salt nature. The combined retention mechanism of specific H-bonding and nonspecific hydrophobic interactions is proposed.

Separation Mechanisms of Co(III) Complexes with EDTA-Type Ligands during Salting-Out TLC on Impregnated and Non-Impregnated Silica Gel