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A new method for the simultaneous determination of tin, lead, cadmium, and mercury in tobacco and tobacco additive by reversed-phase high-performance liquid chromatography combined with microwave digestion and an online enrichment technique is developed. The tin, lead, cadmium, and mercury ions are precolumn derivatized with tetra-(4-dimethylaminophenyl)-porphyrin (T 4 -DMAPP) to form color chelates. The Sn-T 4 -DMAPP, Hg-T 4 -DMAPP, Cd-T 4 -DMAPP, and Pb-T 4 -DMAPP chelates are absorbed onto the front of the enrichment column using a buffer solution of 0.05 mol/L pyrrolidine-acetic acid (pH = 10.0) as the mobile phase. After the concentration is finished (by switching the six-port switching valve) the retained chelates are back-flushed by the mobile phase and move to the analytical column. The chelate separation on the analytical column is satisfactory using gradient elution with methanol (containing 0.05 mol/L pyrrolidine-acetic acid buffer salt, pH = 10.0) and tetrahydrofuran (containing 0.05 mol/L pyrrolidine-acetic acid buffer salt, pH = 10.0). The linearity range is 0.01–120 µg/L for each metal ion. The detection limits (S/N = 3) of tin, lead, cadmium, and mercury are 0.6, 0.8, 0.5, and 0.6 ng/L, respectively. This method is applied to the determination of tin, lead, cadmium, and mercury in tobacco and it's additive with good results.

Simultaneous Determination of Four Heavy Metal Ions in Tobacco and Tobacco Additive by Online Enrichment Followed by RP-HPLC and Microwave Digestion