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Following the recent discovery of a bulk photovoltaic effect in thePb[(Mg1/3Nb2/3)0.68Ti0.32]O3 crystal, we report here more than one order ofmagnitude improvement of photovoltaicity as well as its poling dependence inthe related composition of lead magnesium niobate-lead titanate notedPb[(Mg1/3Nb2/3)0.7Ti0.30]O3. Photocurrent measurements versus light intensityreveal a fascinating hysteretic charge carriers dynamics clearly demonstratingcharge generation, trapping and release processes.

Larger photovoltaic effect and hysteretic photocarrier dynamics in Pb[(Mg1/3Nb2/3)0.70Ti0.30]O3 crystal