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A novel cascade reaction of Ugi/Pd-catalyzed intramolecular divergent C-H functionalization, which is controlled by solvent effect to achieve the regioselective synthesis of spiro- and fused-cyclopropanated indolines from the Ugi adduct of  N -acylated 2-bromoarylamides.

iop conference series. materials science and engineering

Solvent-Controlled Cascade Reaction of Ugi/Pd-Catalyzed Intramolecular Divergent C-H Functionalization for Regioselective Synthesis of Cyclopropanated N-Heterocycles