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Results: • PTZ development is sensitive to organic layer thickness and nearsurface factors that mediate heat exchange at the atmosphere/ground-surface interface. • PTZ evolution and groundwater discharge are greatest in spring and fall. • PTZs serve as a detectable precursor to accelerated permafrost degradation. • Timing of increased baseflow and flowpath depths are significant for evaluating dissolved organic carbon (DOC), total dissolved nitrogen (TDN), and mercury mobilization as well as for the transport of mineral weathering products.

Development of perennial thaw zones in boreal hillslopes enhances potential mobilization of permafrost carbon