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Small-molecule bulk-heterojunction solar cells utilizing a binary-blended donor material composed of a liquid crystalline phthalocyanine and its analogue have been studied. The short-circuit current density (J sc) and power conversion efficiency (PCE) of the solar cells utilizing the blended donor material with an optimized blend ratio reached 11.6 mA/cm2 and 4.8%, respectively, which were superior to those of organic solar cells utilizing each donor material. The improvement of J sc and PCE has been discussed from the viewpoints of the crystal structure, optical and carrier transport properties of the blended donor material.

Bulk-Heterojunction Thin-Film Solar Cells Utilizing Miscible Binary Donor Materials of Liquid Crystalline Phthalocyanine and its Analogue