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By collision-energy/electron-energy-resolved 2D Penning ionization electron spectroscopy as well as by theoretical calculations of the collisional ionization dynamics, the outer shape of molecular orbitals for ionization to X(2Σ+) and A(2Π) states of CO+ was sensitively probed, and the anisotropy of the interaction between He*(23S) and CO was determined. Ionization to the B(2Σ+) state of CO+ was assigned to autoionization from superexcited states by angle-resolved electron spectroscopy and theoretical simulations.

journal of physics. conference series

Observation of anisotropic interactions and molecular orbitals of CO upon collision with He<sup>*</sup>(2<sup>3</sup>S) atoms by two-dimensional Penning ionization electron spectroscopy

Observation of anisotropic interactions and molecular orbitals of CO upon collision with He*(23S) atoms by two-dimensional Penning ionization electron spectroscopy

Observation of anisotropic interactions and molecular orbitals of CO upon collision with He^*(2³S) atoms by two-dimensional Penning ionization electron spectroscopy