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Anion-deficient corundum and TLD-500 detectors on their basis were studied for a possible correlation between the thermoluminescence (TL) yield in the high-temperature TL peak at 830 K and the transformation of intrinsic defects and contents of impurities. Only 40– 60% of TLD-500 detectors were found to have 830 K TL peak. The efficiency of thermally stimulated direct conversion of F and F + centers in the 800–930 K region depends on the presence of TL peak at 830 K. Obtained data point to the quenching role of the Ti impurity in the formation of the 830 K TL peak. Also, these data provide indirect evidence of association of the 830 K TL peak with Cr 3+ ions.

High-temperature thermoluminescence of anion-deficient corundum and its connection with intrinsic defects and impurities