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The local atomic structure and dynamics in multiferroic MnWO4 and Mn0.7Co0.3WO4 have been studied by X-ray absorption spectroscopy at the Co(Mn) K-edge and W L3-edge. The analysis of the first coordination shell of metal ions using single-shell Gaussian approximation and regularization-like method allowed us to determine a distortion of Mn(Co)O6 and WO6 octahedra. It was found that the local environment of Co2+ ions in Mn0.7Co0.3WO4 is close to that in CoWO4, whereas the presence of cobalt ions reduces the distortion of MnO6 octahedra in comparison with pure MnWO4.

Effect of cobalt doping on the local structure and dynamics of multiferroic MnWO4and Mn0.7Co0.3WO4

Effect of cobalt doping on the local structure and dynamics of multiferroic MnWO₄and Mn_0.7Co_0.3WO₄