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A study of the applicability of the variational treatments based on using ofthe modified Lang-Firsov unitary transformation (MLF method) in theinvestigation of the vibron self-trapped states in biological macromolecularchains are presented. We compare the values of the ground state energypredicted by MLF methods with the values of the ground state energy predictedby the standard small-polaron theory, for various values of the basic energyparameters of the system. We obtain regions in system parameter space where MLFapproach gives better description of the vibron states.

Vibron Self--trapped States in Biological Macromolecules: Comparison of Different Theoretical Approaches