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Spectacular trends in the modification of the Xe 5s photoionization viainterchannel coupling with confinement resonances emerging in the Xe 4d giantresonance upon photoionization of the Xe@C60, Xe@C240 and Xe@C60@C240endo-fullerenes are theoretically unraveled and interpreted.

5s correlation confinement resonances in Xe-endo-fullerenes