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The alkali fulleride Rb4C60 has been investigated by studies of the resistance and by Raman spectroscopy under pressures up to 2 GPa and 13 GPa, respectively. Our data show a reversible phase separation into metallic Rb3C60 and Rb6C60 at pressures above 1 GPa. The reversibility indicates that the phase separation primarily occurs on the nanometer length scale. The data explain several puzzling results reported in the recent literature.<p>OPEN ACCESS. Editor in Chief: Kenichi Takemura. Editorial Board: Tadashi Kondo, Hitoshi Matsuki, Nobuyuki Matubayasi, Yoshihisa Mori, Osamu Ohtaka, Chihiro Sekine</p

Reversible nano-scale phase separation of Rb4C60under pressure

Reversible nano-scale phase separation of Rb₄C₆₀under pressure