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We report new time-resolved synchrotron x-ray diffraction (SXRD) measurementsto track structural transformations in calcium-aluminate (CaO)x(Al2O3)1-xliquids during glass formation, and review recent progress in neutrondiffraction with isotope substitution (NDIS) experiments, combined withaspherical ion model molecular dynamics (AIM-MD) simulations, to identify theatomic-scale configurational constraints on glass-forming ability.

Configurational constraints on glass formation in the liquid calcium aluminate system