Comment on ‘Electronic structure of Mo(1−x)Rexalloys studied through resonant photoemission spectroscopy’
Author(s) -
Prescott E. Evans,
P. A. Dowben
Publication year - 2017
Publication title -
journal of physics condensed matter
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.908
H-Index - 228
eISSN - 1361-648X
pISSN - 0953-8984
DOI - 10.1088/1361-648x/aa4d75
Subject(s) - alloy , photoemission spectroscopy , electronic structure , materials science , short range order , binary number , order (exchange) , condensed matter physics , binary alloy , bond length , spectroscopy , atomic physics , crystallography , x ray photoelectron spectroscopy , chemistry , physics , crystal structure , nuclear magnetic resonance , metallurgy , quantum mechanics , mathematics , economics , arithmetic , finance
Further analysis of the resonant photoemission data, found within Sundar et al (2016 J. Phys.: Condens. Matter 28 315502), show the intensities do not follow the elemental composition in the Mo Re alloy. Similar trends are observed in the published data for Gd Ni alloy films. The analysis of the resonant photoemission intensities suggests that Mo in the Mo Re alloy and Gd in the Gd Ni alloy have nearest neighbor bonds to Re and Ni respectively. This means the A-B bond is favored over the average of the A-A bond and the B-B bond in these binary alloys, so that the short range order favors strong local ordering rather than clustering alloys.
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