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The isoscaling and isobaric ratio difference (IBD) methods are used to studythe $\Delta\mu/T$ ($\Delta\mu$ being the difference between the chemicalpotentials of neutron and proton, and $T$ being the temperature) in themeasured 1$A$ GeV $^{124}$Sn + $^{124}$Sn, $^{112}$Sn + $^{112}$Sn, $^{136}$Xe+ Pb and $^{124}$Xe + Pb reactions. The isoscaling phenomena in the$^{124}$Sn/$^{112}$Sn and the $^{136}$Xe/$^{124}$Xe reactions pairs areinvestigated, and the isoscaling parameter $\alpha$ and $\beta$ are obtained.The $\Delta\mu/T$ determined by the isoscaling method (IS--$\Delta\mu/T$) andIBD method (IB--$\Delta\mu/T$) in the measured Sn and Xe reactions arecompared. It is shown that in most of fragments, the IS-- and IB--$\Delta\mu/T$ are consistent in the Xe reactions, while the IS-- and IB--$\Delta\mu/T$ are only similar in the less neutron-rich fragments in the Snreactions. The shell effects in IB--$\Delta\mu/T$ are also discussed.

Chemical Property of Colliding Sources in 124,136Xe and 112,124Sn Induced Collisions in Isobaric Ratio Difference and Isoscaling Methods