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The effect of local structure on the magnetic and transport properties of thelayered perovskites has been investigated. The samplesPrBaCo$_{2}$O$_{5+\delta}$, ($\delta$ = 0.80 and 0.67) though crystallize inthe same 112 type tetragonal structure have different magnetic ground states.Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy has been employedto explain the changes in magnetic interactions based on the rotation andtilting of CoO polyhedra in these oxygen rich double perovskites.

Influence of local structure on magnetic properties of Layered Cobaltites PrBaCo_2O{5+\delta}, \delta > 0.5