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The ferroelectric order and magnetic field induced effects observed in thespiral phase of MnWO4 are described theoretically. It is demonstratedexplicitly that the Dzyaloshinskii-Moriya antisymmetric interactions contributeto the correlation between spins and electric dipoles in the incommensurate andcommensurate ferroelectric phases of magnetic multiferroics. However, othersingle-site symmetric interactions are shown to be involved in themagnetoelectric process, suggesting the possible existence of an electricpolarization originating from purely symmetric effects.

Directional magnetoelectric effects in MnWO4: magnetic sources of the electric polarization