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A VO2 single-crystal has been subject of a combined investigation by highresolution XPS, x-ray emission spectroscopy with electron and energy-selectivex-ray excitation (V L-alpha, V K-beta-5- and O K-alpha emission) and x-rayabsorption spectroscopy (O1s). We performed first principles tight-binding LMTOband structure calculations of VO2 in both monoclinic and tetragonal rutilestructures and compare the densities of states with the experimental data. Fromthis we conclude that the electronic structure of VO2 is more bandlike thancorrelated.Comment: 12 pages, 5 figures, uses ioplppt.sty. To be published in J.Phys.:C

Electronic structure of studied by x-ray photoelectron and x-ray emission spectroscopies