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X-ray single-photon ionization and fragmentation of the chiral moleculehalothane (CHBrClCF${}_{3}$) from a racemic mixture have been investigatedusing the COLTRIMS (Cold Target Recoil Ion Momentum Spectroscopy) technique.Two important facets related to the core ionization of this species areexamined: Firstly, the distinction of enantiomers (mirror isomers) and thedetermination of absolute configuration on a single-molecule level by four-bodyCoulomb explosion; secondly, the interplay of site-selective excitation andfragmentation patterns. These results are easily transferrable to othermolecular species and show the wealth of features

Stereochemical configuration and selective excitation of the chiral molecule halothane