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Luminescence spectra corresponding to transitions from β1g, G1g, D'2g, and ion-pair states of an iodine molecule to weakly bound valence states 1u, 2u, and , correlating with the I(2P3/2) + I(2P1/2) (ab) and I(2P1/2) + I(2P1/2) (bb) dissociation limits, respectively, have been observed and analyzed. Energies of vibrational levels, spectroscopic constants, and potential energy curves of the valence states have been determined. The state is shown to be bound by 488(2) cm−1 and placed lower than 1u(bb) and (bb), unlike ab initio estimations.

Spectroscopic constants and potential energy curves of some iodine valence ungerade weakly bound states