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Powerful hybridization of the Cd 4$d$ state with the $d$-angular momentumstate of C$_{60}$ $\pi$ symmetry is found in the local density approximation(LDA) structure of Cd@C$_{60}$ ground state. The photoionization of theresulting symmetric and antisymmetric levels are computed using the timedependent LDA method to include electron correlations. Cross sections exhibiteffects of the C$_{60}$ plasmonic motion coherently coupled to thediffraction-type cavity oscillations induced by local emissions from C$_{60}$.The Cd@C$_{60}$ results exhibit a substantial difference from our previousresults for Zn@C$_{60}$.

Photoionization of bonding and antibonding-type atom-fullerene hybrid states in Cd@C$_{60}$ vs Zn@C$_{60}$60