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We report a systematic study on the effect of partial substitution ofSc$^{3+}$ by Ti$^{4+}$ in Sr$_{2}$ScFeAsO$_{3}$, Ca$_{2}$ScFeAsO$_{3}$ andSr$_{3}$Sc$_{2}$Fe$_{2}$As$_{2}$O$_{5}$ on their electrical properties. Highlevel of doping results in an increased carrier concentration and leads to theappearance of superconductivity with the onset of T$_{c}$ up to 45 K.

Possible high temperature superconductivity in Ti-doped A-Sc-Fe-As-O (A= Ca, Sr) system