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This work reports about electronic structure calculations for the Heuslercompound Co$_2$FeAl$_{1-x}$Si$_x$. Particular emphasis was put on the role ofthe main group element in this compound. The substitution of Al by Si leads toan increase of the number of valence electrons with increasing Si content andmay be seen as electron-doping. Self-consistent electronic structurecalculations were performed to investigate the consequences of the electrondoping for the magnetic properties. The series Co$_2$FeAl$_{1-x}$Si$_x$ isfound to exhibit half-metallic ferromagnetism and the magnetic moment followsthe Slater-Pauling rule. It is shown that the electron-doping stabilises thegap in the minority states for $x=0.5$.Comment: J. Phys. D (accepted

Substituting the main group element in cobalt–iron based Heusler alloys: Co2FeAl1−xSix

Substituting the main group element in cobalt–iron based Heusler alloys: Co₂FeAl_1−xSi_x