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Complex Organic Molecules (COMs) are considered crucial molecules, since theyare connected with organic chemistry, at the basis of the terrestrial life.More pragmatically, they are molecules in principle difficult to synthetize inthe harsh interstellar environments and, therefore, a crucial test forastrochemical models. Current models assume that several COMs are synthesisedon the lukewarm grain surfaces ($\gtrsim$30-40 K), and released in the gasphase at dust temperatures $\gtrsim$100 K. However, recent detections of COMsin $\lesssim$20 K gas demonstrate that we still need important pieces tocomplete the puzzle of the COMs formation. We present here a complete census ofthe oxygen and nitrogen bearing COMs, previously detected in different ISMregions, towards the solar type protostar IRAS16293-2422. The census wasobtained from the millimeter-submillimeter unbiased spectral survey TIMASSS.Six COMs, out of the 29 searched for, were detected: methyl cyanide, ketene,acetaldehyde, formamide, dimethyl ether, and methyl formate. The multifrequencyanalysis of the last five COMs provides clear evidence that they are present inthe cold ($\lesssim$30 K) envelope of IRAS16293-2422, with abundances 0.03-2$\times 10^{-10}$. Our data do not allow to support the hypothesis that theCOMs abundance increases with increasing dust temperature in the cold envelope,as expected if COMs were predominately formed on the lukewarm grain surfaces.Finally, when considering also other ISM sources, we find a strong correlationover five orders of magnitude, between the methyl formate and dimethyl etherand methyl formate and formamide abundances, which may point to a link betweenthese two couples of species, in cold and warm gas.

The census of complex organic molecules in the solar type protostar IRAS16293-2422